I just installed Vector today and I'm impressed. I've not had any major problems getting things running but I must admit I'm puzzled as to how to automatically move an application to a specific desktop. For example I want to move Thunderbird to Desktop 4, Exaile to Desktop 3 etc. when they start up. I assume this is possible with XFCE, and I know how to do it in OpenBox on Arch.
Any help is much appreciated.